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Pure alumina (Al 2 O 3 ) is recovered from alunite (Al 2 (SO 4 ) 3 .K 2 SO 4 .4 Al (OH) 3 ) which is found mixed with various impurities by first calcinating the alunite in the presence of a chloride to produce impure Al 2 O 3 and other biproducts, and the impure Al 2 O 3 is then contacted with concentrated HCl to produce, after concentration and crystallization, crystals of AlCl 3 .6H 2 O.

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Alunite is a semisoluble salt type mineral and when brought in contact with water it will extensively react with water to yield various aluminum and potassium species. The equilibrium abundance of these species has been calculated as a function of pH by using the available equilibrium data which include the following reactions.